In order to apply a nation must not have declared war during their year of application. The nation must be willing to oblige by the charter and all rules. The nation must be willing to basically have an alliance with all the nations in the Union. The nation must get 2/3 vote from the general assembly and no veto's from the Security Council (look at Security Council page for more info). After that the nation will get a response if their application was accepted or rejected.
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